CALIFORNIA AIR RESOURCES BOARD State Building Auditorium, Room 1138 107 South Broadway Los Angeles, CA August 13, 1987 10:00 a.m. AGENDA Page 87-11-1 Consideration of Status Report on Clean Air Act Issues of Concern to California. 87-11-2 Public Hearing to Consider Amendments to 001 Regulation Regarding the Degree of Unsaturation of Gasoline Sold as Motor Vehicle Fuel in the South Coast Air Basin. 87-11-3 Status Report on Efforts to Develop Clean Diesel 048 Fuel. Other Business a. Closed Session 1. Personnel (as authorized by State Agency Open Meeting Act, Govt. Code Sec. 11126(a).). 2. Litigation (Pursuant to the attorney-client privilege, Evidence Code Sec. 950-962, and Govt. Code Sec. 11126(q).). b. Research Proposals c. Delegations to Executive Officer ITEM NO.: 87-11-2 Public Hearing to Consider Amendments to Regulation Regarding the Degree of Unsaturation of Gasoline Sold as Motor Vehicle Fuel in the South Coast Air Basin. RECOMMENDATION The staff recommends that the Board adopt and incorporate in Section 2250, Title 13, California Administrative Code, and updated version of the current test method for the bromine number of gasoline with a provision explicitly stating that the method applies to blends of gasoline containing ethanol, methanol, tert-butyl alcohol (TBA), and methyl tert-butyl ether (MTBE). The staff also recommends that the Board amend the regulation to clarify the definition of gasoline. DISCUSSION Section 2250 limits the degree of unsaturation of gasoline sold or supplied as a motor vehicle fuel in the South Coast Air Basin (SCAB) to that indicated by a bromine number of 30. The bromine number, a measure of the degree of unsaturation, is roughly two times the olefin content of gasoline. The olefin content of gasoline evaporative emissions is dependent on the olefin content of the gasoline. Olefins generally react more rapidly than other hydrocarbons. The regulation was adopted to place a cap on the olefin content of gasoline to control the reactivity of gasoline-related emissions. The method presently referenced in the regulation is ASTM D 1159-77. The method states that it is not generally applicable to gasoline with blending agents such as ethers, alcohols, ketones or aminoes. Recent data from ARCO Chemical Company and from the ARB Haagen-Smit Laboratory indicate that the bromine numbers, as measured with ASTM test method D 1159-77, of blends of gasoline with either methanol, ethanol, TBA or MTBE are not significantly different than the bromine number of the base gasoline in the blend. SUMMARY AND IMPACTS OF PROPOSED BOARD ACTION Adoption of the proposed test method would enhance enforcement of the bromine number regulation with reference to the subject blends. The proposed action is not expected to create significant costs or savings to any public agency or private entity. ITEM NO.: 87-11-3 Status Report on Diesel Fuel and Its Effects on Emissions from Diesel Motor Vehicles. RECOMMENDATION This is a status report. The staff is not making a recommendation. DISCUSSION The Board's diesel vehicle emission control program.-The Air Resources Board has had for a number of years a program to control emissions from diesel vehicles. The Board has established strict exhaust emission standards for diesel vehicles and has adopted strict requirements for the sulfur content of diesel fuel sold in the South Coast Air Basin. In addition to these past actions, the Board has a continuing program to investigate additional strategies to reduce further emissions from diesel vehicles. Some of the elements of that program are the evaluation of vehicular emission standards, hardware retrofits, alternative fuels, and an inspection and maintenance program. In addition to those control strategies, the evaluation of modifications to conventional diesel fuel - the subject of this report - is another element of the Board's diesel vehicle emission reduction program. Where we are now.-It is well known that diesel fuel quality affects diesel engine emissions. However, the extent of the fuel quality-emissions relationship has not been well established. Results of studies that are to be completed in the near future will allow the staff to evaluate more completely diesel fuel modifications as a control strategy. The staff will then present its findings for the Board's consideration. What we know.-Based on limited data that are now available, diesel motor vehicle emissions of particulate matter (soot) can be reduced up to perhaps 50 percent by reducing the concentration of aromatic hydrocarbons in the fuel. Aromatic hydrocarbons have been identified as a major variable in the formation of soot emissions from diesel engines. Fuel sulfur content also affects diesel engine particulate emissions, but not the soot emissions. Sulfur dioxide emissions, which result from sulfur in the fuel, are converted to particulate matter in the atmosphere. What we don't know.-The current state of knowledge regarding the effects of fuel quality on diesel engine emissions is not complete. Although it is known that aromatic hydrocarbons in the fuel affect soot emissions, it is not known by how much they are affected. Different studies have given different results. Also, the effects of fuel quality on emissions of other pollutants are less well known. Much of the data that are now available were obtained on light-duty engines. Heavy-duty engines are the major contributors to diesel vehicle emissions, and less is known about the effects of fuel quality on these engines. Some studies have given contradicting results. The cost to reduce emissions from diesel vehicles is also uncertain. Forthcoming additional emissions-fuel quality data.-There is a major study now in progress that will provide a more certain basis for evaluating the relationship between fuel quality and diesel emissions. The study is being conducted on four heavy-duty diesel engines - the engines that are the source of most diesel emissions. This study, sponsored by the Coordinating Research Council (CRC) with ARB participation, will also provide information on the relationship, if any, between diesel fuel composition and benzene emissions. Forthcoming additional cost data.-Another area of uncertainty is the cost of modifying diesel fuel properties. The staff has made some cost estimates based on a three-year old survey of California oil refiners. To obtain a more complete cost estimate, the ARB has contracted with A.D. Little to perform a linear programming study of California refineries to obtain an independent cost estimate of various changes to motor vehicle diesel fuel specifications. Our Schedule.-When the additional data on cost and the data on the fuel quality-emissions relationship are available, the staff will present its findings to the Board in a formal report. The cost study information is scheduled to be available in January 1988, and the fuel quality-emissions data are scheduled to be available in the second quarter of 1988. The staff has planned for workshops on the various issues related to fuel modification. A workshop is scheduled for the fall of 1987, and others are planned to be held following the availability of the emissions and cost study data. Staff regulatory proposals, if justified, can be heard by the Board six months after receipt of the results of the CRC study on fuel quality and emissions.